Ramberg-Ba cklund reactions of thian-4-one derivatives.

by Guy Casy

Publisher: University of East Anglia in Norwich

Written in English
Published: Downloads: 601
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Edition Notes

Thesis (Ph.D), University of East Anglia, School of Chemical Sciences, 1987.

ID Numbers
Open LibraryOL13924381M

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Ramberg-Ba cklund reactions of thian-4-one derivatives. by Guy Casy Download PDF EPUB FB2

The application of the Ramberg-Backlund reaction in the conversion of several 3,n-dithiabicyclo[n]alkatrienes to the corresponding bicyclo[n]alkapentaenes is reported.

In book: Name Reactions, pp Cite this publication Aigialomycin D Using a Ramberg-Backlund/RCM Strategy. contrast underwent epimerization at C-4 to generate the α-L-lyxo derivatives. Organic Reactions, Volume 62 includes chapters such as "The Ramberg-Backlund Reaction," "a -Hydroxylation of Enolates and Silyl Enol Ethers," "The a -Hydroxyl Ketone (a -Ketol) and Related Rearrangements," and " Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives.

The first synthesis of the tetracyclic nucleus of Ramberg-Ba cklund reactions of thian-4-one derivatives.

book Integrastatins, natural products that have been shown to selectively inhibit HIV-1 integrase, is reported. Key steps of this synthesis involve a novel cis-selective Ramberg−Bäcklund reaction Cited by: Organic Reactions, Volume 62 includes chapters such as 'The Ramberg-Backlund Reaction,' 'a -Hydroxylation of Enolates and Silyl Enol Ethers', 'The a -Hydroxyl Ketone (a -Ketol) and Related Rearrangements,' and 'Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives'.

A thiolate anion addition to an enone and a Ramberg-Backlund reaction were other noteworthy steps for the completion of the synthesis of (+)-fawcettidine.

Chapter 3 describes the platinum(II)- and gold(I)-catalyzed cyclorearrangement of 1,2,3,4-tetrahydropyridine derivatives. "Organic Reactions, Volume 62" includes chapters such as 'The Ramberg-Backlund Reaction,' 'a -Hydroxylation of Enolates and Silyl Enol Ethers', 'The a -Hydroxyl Ketone (a -Ketol) and Related Rearrangements,' and 'Transformation of Glycals into 2,3-Unsaturated Glycosyl Derivatives'.

The Bartoli reaction is a classic method for the preparation of azaindole substrates, 18 with the potential to offer significant advantages in terms of prefunctionalization at C4.

Adaptation of this approach to. Select Publications Select Publications. By Professor Richard John Taylor. Journal articles Paterson DE; Taylor RJK,'Ramberg - Backlund approaches to the synthesis of C-linked disaccharides', Angewandte Chemie - International Edition, [,0]decene and its Derivatives.

Select Publications Select Publications. By Professor Richard John Taylor'The Epoxy-Ramberg-Backlund reaction: A new route to allylic alcohols', Tetrahedron Letters, vol. 38 'Organolithium additions to styrene derivatives. Organic Chemistry Portal. The Organic Chemistry Portal offers an overview of recent topics, interesting reactions, and information on important chemicals for organic chemists.

Archive:,, More Reactions. You can write a book review and share your experiences. Other readers will always be interested in your opinion of the books you've read.

Whether you've loved the book or not, if you give your honest and detailed thoughts then people will find new books. Reactions and Syntheses in the Organic Chemistry Laboratory ISBN: Hudlicky, Tomas / Reed, Josephine W. The Way of Synthesis Evolution of Design and Methods for Natural.

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Wharton Reaction, in Name Reactions for Functional Group Transformations, Jie Jack Li, Ed., Wiley: Hoboken, NJ,pp Design and Synthesis of 9-Octyl-Benzolactam-V9, A Selective.

l-glutamic acid/n-acyliminium ions/alpha-amino-acids/occurring 4-alkylideneglutamic acids/angiotensin-converting enzyme/semicorrin metal-complexes/chiral starting material/bacillus-pumilus ai/gamma-lactam analogs/diels-alder reaction. Abstract. C-glycosides have attracted much attention, considering that many of them have demonstrated their effectiveness as therapeutic increasing significance of C-glycosides is.

Hexahydro[]paracyclophane (6) and related compounds were prepared from the extrusion of sulfur dioxide from 2,dithia-4,5,6,7,8,9-hexahydro[]paracyclophane 2,2,11,tetraoxide (9) by either the Ramberg−Backlund reaction Cited by: Formylation of benzo[b]furo[b]pyrrolecarboxylic acid derivative () under conditions of the Vilsmeier reaction gave the 3-formylated product () which has been used as a starting material for.

Li's book contains reactions of all mechanistic classes The book is nicely balanced, containing modern-day reactions for assembly of stereocomplex molecules.

Reactions such as the Corey-Bakshi-Shibata reduction are analyzed. This book /5(16). Organic Reactions is a comprehensive series of volumes composed of chapters devoted to important synthetic reactions.

World-renowned experts, who have extensive hands-on experience in this field, have written the chapters that comprise this volume. The chemistry is presented from a preparative point of view, with particular attention given to reaction Author: Larry E.

Overman. Reaction of 1,1-di-p-methoxyphenyl-2,2-dinitroethylene and 1,1-di-O-methoxyphenyl-2,2-dinitroethylene with 1-benzyl-1,4-dihydronicotinamide: evidence for concerted electron-hydrogen atom transfer.

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It covers over classical as well as contemporary name reactions. Chapter One A. Acyloin Ester Condensation [alpha]-Hydroxyketones from carboxylic esters. Upon heating of a carboxylic ester 1 with sodium in an inert solvent, a condensation reaction can take place to yield a [alpha]-hydroxy ketone 2 after hydrolytic workup.

This reaction Brand: Wiley. There is an Open Access version for this licensed article that can be read free of charge and without license restrictions. The content of the Open Access version may differ from that of the licensed version.

'The reactions of diazo compounds with lactones. Part 2. The reaction of cyclic 2-diazo-1,3-dicarbonyl compounds with diketene: benzofuran formation' Murphy, PV,O'Sullivan, TJ,Kennedy, BD,Geraghty, NWA () 'The reactions.

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